Thursday, January 6, 2011

Chemical Bonding

Project in Chemistry IV (3rd Grading)
-Jonathan Millora
-Bob Joseph Calaluan

What is Chemical Bonding? :)


Chemical bonding happens when atoms from two or more different elements combine to form a new substance. An atom is made of three different subatomic particles. Inside the nucleus, there are protons that have a positive charge and neutrons that have no charge. Circling the nucleus are electrons containing a negative charge. These electrons combine causing the elements to chemically bond. 

There are certain types of chemical bonding. In this blog, shows four different types of chemical bonding:

>Covalent Bond
  >Polar Covalent Bond

>Ionic Bond

>Metallic Bonds

>Hydrogen Bonding




Covalent Bonds

     Covalent chemical bonds involve the sharing of a pair of valence electrons by two atoms, in contrast to the transfer of electrons in ionic bonds. Such bonds lead to stable molecules if they share electrons in such a way as to create a noble gas configuration for each atom.

          **Note: Hydrogen gas forms the simplest covalent bond in the diatomic hyrdrogen. The halogens such as chlorine also exist as diatomic gases by forming covalent bonds. The nitrogen and oxygen which makes up the bulk of the atmosphere also exhibits covalent bonding in forming diatomic molecules.



So, what are Polar Covalent Bonds!!!?? :)

     Covalent Bonds in which the sharing of the electron pair is unequal, with the electrons spending more time around the more nonmetallic atom, are called polar covalent bonds. In such a bond there is a charge separation with one atom being slightly more positive and the other more negative, i.e., the bond will produce a dipole moment. The ability of an atom to attract electrons in the presence of another atom is a measurable property called electronegativity.




Ionic Bonds

In this chemical bond, atoms can either transfer or share their valence electrons. In the extreme case where one or more atoms lose electrons and other atoms gain them in order to produce a noble gas electron configuration, the bond is called an ionic bond.

   Examples are Alkali Halides such as Sodium Chloride. :D





Metallic Bonds

The properties of metals suggest that their atoms possess strong bonds, yet the ease of conduction of heat and electricity suggest that electrons can move freely in all directions in a metal. The general observations give rise to a picture of "positive ions in a sea of electrons" to describe metallic bonding.

Shown below are the different properties of Metal:

Hardness


Hardness refers to the ability of a metal to resist abrasion, penetration, cutting action, or permanent distortion. Hardness may be increased by working the metal and, in the case of steel and certain titanium and aluminum alloys, by heat treatment and cold-working (discussed later). Structural parts are often formed from metals in their soft state and then heat treated to harden them so that the finished shape will be retained. Hardness and strength are closely associated properties of all metals.

Brittleness
Brittleness is the property of a metal that allows little bending or deformation without shattering. In other words, a brittle metal is apt to break or crack without change of shape. Because structural metals are often subjected to shock loads, brittleness is not a very desirable property. Cast iron, cast aluminum, and very hard steel are brittle metals.

Malleability
A metal that can be hammered, rolled, or pressed into various shapes without cracking or breaking or other detrimental effects is said to be malleable. This property is necessary in sheet metal that is to be worked into curved shapes such as cowlings, fairings, and wing tips. Copper is one example of a malleable metal.

Ductility
Ductility is the property of a metal that permits it to be permanently drawn, bent, or twisted into various shapes without breaking. This property is essential for metals used in making wire and tubing. Ductile metals are greatly preferred for aircraft use because of their ease of forming and resistance to failure under shock loads. For this reason, aluminum alloys are used for cowl rings, fuselage and wing skin, and formed or extruded parts, such as ribs, spars, and bulkheads. Chrome-molybdenum steel is also easily formed into desired shapes. Ductility is similar to malleability.

Elasticity
Elasticity is that property that enables a metal to return to its original shape when the force that causes the change of shape is removed. This property is extremely valuable, because it would be highly undesirable to have a part permanently distorted after an applied load was removed. Each metal has a point known as the elastic limit, beyond which it cannot be loaded without causing permanent distortion. When metal is loaded beyond its elastic limit and permanent distortion does result, it is referred to as strained. In aircraft construction, members and parts are so designed that the maximum loads to which they are subjected will never stress them beyond their elastic limit.
NOTE: Stress is the internal resistance of any metal to distortion.

Toughness
A material that possesses toughness will withstand tearing or shearing and may be stretched or otherwise deformed without breaking. Toughness is a desirable property in aircraft metals.

Density
Density is the weight of a unit volume of a material. In aircraft work, the actual weight of a material per cubic inch is preferred, since this figure can be used in determining the weight of a part before actual manufacture. Density is an important consideration when choosing a material to be used in the design of a part and still maintain the proper weight and balance of the aircraft.

Fusibility
Fusibility is defined as the ability of a metal to become liquid by the application of heat. Metals are fused in welding. Steels fuse at approximately 2,500°F, and aluminum alloys at approximately 1, 110°F.

Conductivity
Conductivity is the property that enables a metal to carry heat or electricity. The heat conductivity of a metal is especially important in welding, because it governs the amount of heat that will be required for proper fusion. Conductivity of the metal, to a certain extent, determines the type of jig to be used to control expansion and contraction. In aircraft, electrical conductivity must also be considered in conjunction with bonding, which is used to eliminate radio interference. Metals vary in their capacity to conduct heat. Copper, for instance, has a relatively high rate of heat conductivity and is a good electrical conductor.


Contraction and Expansion

Contraction and expansion are reactions produced in metals as the result of heating or cooling. A high degree of heat applied to a metal will cause it to expand or become larger. Cooling hot metal will shrink or contract it. Contraction and expansion affect the design of welding jigs, castings, and tolerances necessary for hot-rolled material.
 Hydrogen Bonding

>Hydrogen bonding differs from other uses of the word "bond" since it is a force of attraction between a hydrogen atom in one molecule and a small atom of high electronegativity in another molecule. That is, it is an intermolecular force, not an intramolecular force as in the common use of the word bond.

>When hydrogen atoms are joined in a polar covalent with a small atom of high electronegativity such as O, F or N, the partial positive charge on the hydrogen is highly concentrated because of its small size. If the hydrogen is close to another oxygen, fluorine or nitrogen in another molecule, then there is a force of attraction termed a dipole-dipole interaction. This attraction or "hydrogen bond" can have about 5% to 10% of the strength of a covalent bond.

>Hydrogen bonding has a very important effect on the properties of water and ice. Hydrogen bonding is also very important in proteins and nucleic acids and therefore in life processes. The "unzipping" of DNA is a breaking of hydrogen bonds which help hold the two strands of the double helix together


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